Reaction of 9-amino(phenylamino)methylene- and 9-α-aminobenzylidene-4-azafluorenes with some electrophilic reagents

Authors

  • А. B. Варламов Russian University of National Friendship, Moscow 117198
  • А. Н. Левов Russian University of National Friendship, Moscow 117198
  • B. B. Давыдов Russian University of National Friendship, Moscow 117198
  • А. Э. Алиев Russian University of National Friendship, Moscow 117198
  • А. П. Крапивко Russian University of National Friendship, Moscow 117198
  • Г. B. Шебан Russian University of National Friendship, Moscow 117198
  • А. И. Скоморохова Russian University of National Friendship, Moscow 117198
  • Б. E. Зайцев Russian University of National Friendship, Moscow 117198
  • Н. C. Простаков Russian University of National Friendship, Moscow 117198

Abstract

It was shown that initial protonation of 9-aminomethylene-4-azafluorene takes place at the pyridine nitrogen atom. In nitrosation of this azafluorene, 4-azafluorenone oxime is formed, and in reaction with dichlorocarbene, 1′-amino-2′, 2'-dichlorospiro[4-azafluorene-9,3′-cyclopropane] is formed. Acylation yields mono- or diacyl derivatives as a function of the acylating agent and reaction conditions.

How to Cite
Varlamov, A. V.; Levov, A. N.; Davydov, V. V.; Aliev, A. É.; Krapivko, A. P.; Sheban, G. V.; Skomorokhova, A. I.; Zaitsev, B. E.; 
Prostakov, S. N. Chem. Heterocycl. Compd. 1995, 31, 461. [Khim. Geterotsikl. Soedin. 1995, 527.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01177019

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Published

1995-04-25

Issue

No. 4 (1995)

Section

Original Papers