Formation of <i>o</i>-nitrosoalkylaminobenzenes in the reaction of benzofurazans with alcohols in acidic conditions

Authors

  • B. А. Самсонов Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090
  • Л. Б. Вoлoдарский Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090
  • И. Ю. Багрянская Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090
  • Ю. B. Гатилов Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090
  • М. М. Шакиpoв Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090

Abstract

In the reaction of benzofurazan with isopropanol and cyclohexanol o-nitrosoaalkylaminobenzenes are formed besides 2,2-dialkyl-2H-benzimidazole-oxides. In the instance of 4-aminobenzofurazan only 2-nitroso-3-alkylaminoanilines are obtained. 5-Nitrobenzofurazan reacts with isopropranol in sulfuric acid to form 4-nitro-2-nitrosoisopropylaminobenzene; however, in the instance of 4-nitrobenzofurazan derivatives the formation of o-nitrosoalkylaminobenzenes has not been observed.

How to Cite
Samsonov, V. A.; Volodarskii, L. B.; Bagryanskaya, I. Yu.; Gatilov, Yu. V.; Shakirov, M. M. Chem. Heterocycl. Compd. 1995, 31, 344. [Khim. Geterotsikl. Soedin. 1995, 395.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01373555

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Published

1995-03-25

Issue

No. 3 (1995)

Section

Original Papers