Synthesis and properties of derivatives of <i>sym</i>-triazines. 14. Cyanoethylation of 4,6-disubstituted 2-amino-<i>sym</i>-triazines

Abstract

The cyanoethylation of 4,6-disubstituted 2-amino-sym-triazines containing alkyl, trichloromethyl, and pyridyl groups was studied, and the corresponding dicyanoethyl derivatives were synthesized. It was shown that the yield of the latter and the duration of the reaction depend on the nature of the substituents in the ring of the initial amino-sym-triazines. A method of obtaining 2-(2-cyanoethyl)amino-sym-triazines is proposed based on the decyanoethylation and disproportionation of the dicyanoethyl derivatives as well as the trans-cyanoethylation.

How to Cite
Kelarev, V. I.; Kosbelev, V. N.; Karakhanov, R. A. Chem. Heterocycl. Compd. 1995, 31, 99. [Khim. Geterotsikl. Soedin. 1995, 111.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01171301