Anodic oxidation of methyl-substituted nitrogen-containing heterocyclic compounds at the activated nickel oxide anode

Authors

  • Д. Фельдман Latvian Institute of Organic Synthesis, Riga LV-1006
  • М. Червенка Institute of Catalysis and Surface Physical Chemistry, Krakov
  • Е. Cтох Institute of Catalysis and Surface Physical Chemistry, Krakov
  • М. Шиманска Latvian Institute of Organic Synthesis, Riga LV-1006
  • Е. Хабер Institute of Catalysis and Surface Physical Chemistry, Krakov

Abstract

Methyl derivatives of several nitrogen-containing heterocyclic compounds were converted into the corresponding carboxylic acids by means of electrochemical oxidation at the nickel oxohydroxide anode in alkaline medium, using a nondiaphragm electrolyzer. The oxidation of 2,5-dimethylpyrazine was used to demonstrate the effect of adding chromium (III) and cobalt (II) compounds to the reaction mixture. The composition and electronics state of the anode surface were studied usign X-ray diffraction and XPS methods.

How to Cite
Feldman, D.; Chervenka, M.; Stokh, E.; Shimanska, M.; Khaber, E. Chem. Heterocycl. Compd. 1995, 31, 80. [Khim. Geterotsikl. Soedin. 1995, 90.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01171298

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Published

1995-01-25

Issue

No. 1 (1995)

Section

Original Papers