AN EFFECTIVE ACTIVATION OF PALLADIUM PHOSPHINE COMPLEXES IN AQUEOUS PHASE REACTIONS OF HETEROAROMATIC BORONIC ACIDS WITH ARYL HALIDES

Authors

  • Н. А. Бумагин Moscow M. V. Lomonosov State University
  • И. С. Веселов Moscow M. V. Lomonosov State University
  • Д. С. Белов Moscow M. V. Lomonosov State University

DOI:

https://doi.org/10.1007/1361

Keywords:

heteroaromatic boronic acids, palladium phosphine complexes, water, activation, Suzuki reaction

Abstract

We have developed a simple and effective method for the activation of palladium phosphine complexes in the Suzuki reaction (TON up to 9800, TOF up to 58800 h-1) by selecting an aqueous reaction medium instead of organic solvents. This method was elaborated for a high yield synthesis of heteroaromatic biaryls with furyl and thienyl groups.

How to Cite
Bumagin, N. A.; Veselov, I. S.; Belov, D. S. Chem. Heterocycl. Compd. 2014, 50, 19. [Khim. Geterotsikl. Soedin. 2014, 24.]

For this article in the English edition see DOI 10.1007/s10593-014-1443-1

Author Biographies

Н. А. Бумагин, Moscow M. V. Lomonosov State University

Николай Александрович Бумагин

Ведущий научный сотрудник кафедры органической химии, доктор химических наук, профессор

И. С. Веселов, Moscow M. V. Lomonosov State University

Иван Сергеевич Веселов

К.х.н.,мл.науч. сотр. кафедры органической химии

Д. С. Белов, Moscow M. V. Lomonosov State University

Дмитрий Сергеевич Белов

К.х.н.,мл.науч.стр. кафедры органической химии

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Published

2014-01-14

Issue

No. 1 (2014)

Section

Original Papers