NOVEL OPTICALLY ACTIVE 1,3-AMINOALCOHOLS DERIVED FROM D-GLUCAL
DOI:
https://doi.org/10.1007/20Keywords:
ethyl(phenyl)6-amino-2, 3, 6-trideoxy-alpha-D-glucopyranosides, tri-O-acetyl-D-glucal, piperidine, pyrrolidine, azetidineAbstract
A series of ethyl(phenyl) 6-amino-2,3,6-trideoxy-alfa-D-glucopyranosides (amino=piperidino (Pip), pyrrolidino (Pyr), azetidino (Az), Bu2N) have been prepared from tri-O-acetyl-D-glucal to obtain catalysts for asymmetric synthesis and the starting compounds for the syntheses of other bidentate ligands.
Also published in Chemistry of Heterocyclic Compounds, 2000, 36 (1), pp 40-46