QUATERNIZATION OF ELECTRON-DEFICIENT PYRIDINES CONTAINING TWO ELECTRON-WITHDRAWING SUBSTITUENTS

Authors

  • O. Д. Митькин M. V. Lomonosov Moscow State University
  • М. А. Юровскaя M. V. Lomonosov Moscow State University

DOI:

https://doi.org/10.1007/21

Keywords:

ethoxycarbonylnitropyridines, acetylnitropyridines, cyanonitropyridines, quaternization, nitropyridinium salts

Abstract

Methyl triflate is an efficient agent for the quaternization of nitropyridines containing an additional electron-withdrawing substituent. When triethyloxonium hexachloroantimonate is used as the quaternizing agent, b-elimination occurs with formation of protic pyridinium salt and ethylene.

Authors: O. D. Mit'kin and M. A. Yurovskaya.

English Translation in Chemistry of Heterocyclic Compounds, 2000, 36 (1), pp 47-48

http://link.springer.com/article/10.1007/BF02256843

 

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Published

2012-09-24

Issue

No. 1 (2000)

Section

Original Papers