Studies of stereochemistry of 3-(arylhydrazono)furan-2(3<i>Н</i>)-ones, synthesis of 4-(arylhydrazono)pyridazin-3(1<i>Н</i>)-ones

Authors

  • Оксана А. Майорова N. G. Chernyshevsky Saratov State University
  • Наталья В. Бабкина N. G. Chernyshevsky Saratov State University
  • Алевтина Ю. Егорова N. G. Chernyshevsky Saratov State University

DOI:

https://doi.org/10.1007/2429

Keywords:

4-(arylhydrazono)-4, 5-dihydropyridazin-3(2Н)-one, 3-(arylhydrazono)furan-2(3Н)-one, azo-hydrazone tautomerism, Z/E-isomers, NMR spectroscopy

Abstract

The structural characteristics of 5-aryl-3-(arylhydrazono)furan-2(3Н)-ones accessed via azocoupling of furan-2(3Н)-ones with aryldiazonium salts were established by NMR spectroscopy (including two-dimensional NMR experiments 1H–13C HMQC, 1H–15N HMQC, 1H–13C HMBC, NOE) and X-ray structural analysis techniques. The reaction of synthesized compounds with hydrazine leading to the formation of six-membered heterocycles, hydrazono-substituted 4,5-dihydropyridazin-3(2Н)-ones, was studied.

How to Cite
Maiorova, O. A.; Babkina, N. V.; Egorova, A. Yu. Chem. Heterocycl. Compd. 2015, 51, 514. [Khim. Geterotsikl. Soedin. 2015, 51, 514.]

For this article in the English edition see DOI 10.1007/s10593-015-1730-5

 

Author Biographies

Оксана А. Майорова, N. G. Chernyshevsky Saratov State University

Инситут химии, кафедра органической и биоорганической химии

Наталья В. Бабкина, N. G. Chernyshevsky Saratov State University

к.х.н., Инситут химии, кафедра органической и биоорганической химии

Алевтина Ю. Егорова, N. G. Chernyshevsky Saratov State University

профессор, д.х.н., профессор кафедры органической и биоорганической химии Инситута химии,

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Published

2015-06-30

Issue

Vol. 51 No. 6 (2015)

Section

Original Papers