SYNTHESIS OF 1-(<i>N</i>-NITROPYRAZOLYL)-1<i>Н</i>-TETRAZOLES – A NEW TYPE OF HETERONUCLEAR <i>N</i>-NITROPYRAZOLE DERIVATIVES

Authors

  • Ирина А. Вацадзе N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Ольга В. Серушкина N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Михаил Д. Дутов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Татьяна К. Шкинева N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Кирилл Ю. Супоницкий A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow 119991
  • Богдан И. Уграк N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Игорь Л. Далингер N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

DOI:

https://doi.org/10.1007/2563

Keywords:

NО donors, N-nitropyrazoles, pyrazoles, tetrazoles, multinuclear NMR, N-nitration, X-ray structural study

Abstract

A general method has been developed for the synthesis of  1-pyrazolyl-1Н-tetrazoles, and N-nitration of these compounds was studied. The structural features affecting the direction of nitration were identified. A series of 1-(N-nitropyrazolyl)-1Н-tetrazoles was obtained, representing a new type of heteronuclear N-nitropyrazole derivatives.

How to Cite
Vatsadze, I. A.; Serushkina, O. V.; Dutov, M. D.; Shkineva, T. K.; Suponitsky, K. Yu.; Ugrak, B. I.; Dalinger, I. L. Chem. Heterocycl. Compd. 2015, 51, 695. [Khim. Geterotsikl. Soedin. 2015, 51, 695.]

For this article in the English edition see DOI 10.1007/s10593-015-1760-z

 

Author Biographies

Ирина А. Вацадзе, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

Ирина Анатольевна Вацадзе

Ольга В. Серушкина, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

Ольга Викторовна Серушкина

Михаил Д. Дутов, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

Михаил Дмитриевич Дутов

Татьяна К. Шкинева, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

Татьяна Константиновна Шкинева

Кирилл Ю. Супоницкий, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow 119991

Кирилл Юриевич Супоницкий

Богдан И. Уграк, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

Богдан Иванович Уграк

Игорь Л. Далингер, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

Игорь Львович Далингер

ведущий научный сотрудник, д.х.н.

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Published

2015-09-07

Issue

Vol. 51 No. 8 (2015)

Section

Original Papers