1,4-DIOXINS FROM METHYL PHENYLCHLOROPYRUVATE. COMPETITION OF THE DARZENS, FAVORSKII, AND GABRIEL REACTIONS

Authors

  • В. А. Мамедов A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences
  • С. Цубой Department of Environmental Chemistry and Materials, Okayama University
  • Л. В. Мустакимова A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences
  • Х. Хамамото Department of Environmental Chemistry and Materials, Okayama University
  • А. Т. Губайдуллин A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences
  • И. А. Литвинов A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences
  • Я. А. Левин A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences

DOI:

https://doi.org/10.1007/284

Keywords:

2, 3-dihydro-l, 4-dioxins, 1, methyl phenylchloropyruvate, Darzens reaction, Favorskii reaction, Gabriel reaction, addition-elimination reaction, CH-pi interaction, pi, pi-interaction, intramolecular short contacts, intermolecular short contacts

Abstract

The reaction of methyl phenylchloropyruvate with potassium phthalimide and sodium imidazolide leads to isomeric 2,5-dimethoxycarbonyl-3.6-diphenyl- and 2,6-dimethoxycarbonyl-3,5-diphenyl-1,4-dioxyns.

Authors: V. A. Mamedov, S. Tsuboi, L. V. Mustakimova, H. Hamamoto, A. T. Gubaidullin, I. A. Litvinov, and Ya. A. Levin.

English Translation in Chemistry of Heterocyclic Compounds, 2000, 36 (8), pp 911-922

http://link.springer.com/article/10.1007/BF02256975

Author Biography

Л. В. Мустакимова, A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences

Department of Environmental Chemistry and Materials, Okayama University

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Published

2013-02-08

Issue

No. 8 (2000)

Section

Original Papers