SYNTHESIS OF NITROPHENYL-SUBSTITUTED 1,3-THIAZOLINE-2-THIONES BY OXIRANE RING OPENING WITH SEVERAL DITHIOCARBAMATES

Authors

  • И. В. Кулаков Institute of Organic Synthesis and Coal Chemistry of Kazahstan Republic
  • А. М. Газалиев Institute of Organic Synthesis and Coal Chemistry of Kazahstan Republic
  • О. А. Нуркенов Institute of Organic Synthesis and Coal Chemistry of Kazahstan Republic
  • Д. М. Турдыбеков International Scientific and Production Holding, "Phytochemistry"

DOI:

https://doi.org/10.1007/2954

Keywords:

2-(4-nitrophenyl)oxirane, carbon disulfide, thiazole-2(3H)-thione, intramolecular heterocyclization, X-ray structural analysis

Abstract

Thiazolo-2(3H)-thiones have been prepared by the reaction of triethylamine dithiocarbamates and 4‑nitrophenyloxirane via formation of intermediate 2-hydroxy-2-(4-nitrophenyl)ethyldithiocarbamates with simultaneous dehydrogenation of the thiazolidine ring to a thiazoline. It was found that both the basicity of the starting amines and the temperature influenced the course of the reaction.

How to Cite
Kulakov, I. V.; Gazaliev, A. M.; Nurkenov, O. A.; Turdybekov, D. M. Chem. Heterocycl. Compd. 2010, 46, 490. [Khim. Geterotsikl. Soedin. 2010, 618.]

For this article in the English edition see DOI 10.1007/s10593-010-0536-8

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Published

2016-01-13

Issue

No. 4 (2010)

Section

Original Papers