SATURATED NITROGENCONTAINING HETEROCYCLES. 19. CATALYTIC REDUCTION OF 10- AND 9,10-SUBSTITUTED <i>sym</i>-OCTAHYDROACRIDINIUM SALTS

Authors

  • P. В. Селлер Rostov State University
  • П. В. Решетов Rostov State University
  • Т. С. Селлер Rostov State University
  • А. П. Кривенько Rostov State University

DOI:

https://doi.org/10.1007/297

Keywords:

6, 8-dimethyl-3-chloropyrimido[4, 5-c]pyridazin-5, 7(6H, SH)dione, CH-acids, organometallic compounds, C-nucleophiles, nucleophilic substitution

Abstract

10-Methyl(phenyl)- and 9,10-diphenylperhydroacridines have been obtained by the catalytic reduction of 10- and 9,10-substituted sym-octahydroacridinium salts. Selective reduction of the furan ring occurred in the case of 9-(2-furyl)-10-phenyl-sym-octahydroacridinium perchlorate. The stereoisomeric composition of the reaction products has been established and a probable scheme for their formation has been proposed.

Authors: R. V. Seller, P. V. Reshetov, S. S. Seller, and A. P. Kriven'ko.

English Translation in Chemistry of Heterocyclic Compounds, 2000, 36 (8), pp 971-974

http://link.springer.com/article/10.1007/BF02256983

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Published

2013-02-12

Issue

No. 8 (2000)

Section

Original Papers