ONE-POT SYNTHESIS OF AZACYCLODIYNES BY REACTION OF α,ω-DIACETYLENES WITH 1,5,3-DIOXAZEPANES USING COPPER-CONTAINING CATALYSTS

Authors

  • Гузель Р. Хабибуллина Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075
  • Фируза Т. Зайнуллина Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075
  • Борис И. Кутепов Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075
  • Асхат Г. Ибрагимов Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075
  • Усейн М. Джемилев Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075

DOI:

https://doi.org/10.1007/4150

Keywords:

N-alkyl-substituted 1, 5, 3-dioxazepanes, α, ω-diacetylenes, cyclic propargylamines, aminomethylation, catalysis

Abstract

An effective method has been developed for the synthesis of cyclic propargylamines by aminomethylation of α,ω-diacetylenes with N-alkyl-substituted 1,5,3-dioxazepanes in the presence of copper-containing catalysts.

Authors: Guzel R. Khabibullina*, Firuza T. Zaynullina, Boris I. Kutepov, Askhat G. Ibragimov, Usein M. Dzhemilev

Author Biographies

Гузель Р. Хабибуллина, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075

к.х.н., старший научный сотрудник лаборатории гетероатомных соединений

Фируза Т. Зайнуллина, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075

аспирант лаборатории гетероатомных соединений

Борис И. Кутепов, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075

д.х.н., проф., зав. лабораторией приготовления катализаторов

Асхат Г. Ибрагимов, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075

д.х.н., проф., зав. лабораторией гетероатомных соединений

Усейн М. Джемилев, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa 450075

д.х.н., член-корр. РАН, научный руководитель Института нефтехимии и катализа РАН

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Published

2018-02-16

Issue

Vol. 54 No. 1 (2018)

Section

Short Communications