СН-FUNCTIONALIZATION OF (HETERO)ARENES WITH ETHYNE AND ETHENE MOIETIES

Authors

  • Дмитрий С. Копчук Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002, Russia; I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, ul. S. Kovalevskoi 22 / Akademicheskaya 20, Ekaterinburg 620990, Russia
  • Ольга С. Тания Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, ul. S. Kovalevskoi 22 / Akademicheskaya 20, Ekaterinburg 620990
  • Альберт Ф. Хасанов Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, ul. S. Kovalevskoi 22 / Akademicheskaya 20, Ekaterinburg 620990
  • Алексей П. Криночкин Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, ul. S. Kovalevskoi 22 / Akademicheskaya 20, Ekaterinburg 620990
  • Игорь С. Ковалев Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002
  • Татьяна А. Поспелова Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002
  • Григорий В. Зырянов Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, ul. S. Kovalevskoi 22 / Akademicheskaya 20, Ekaterinburg 620990
  • Владимир Л. Русинов Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, ul. S. Kovalevskoi 22 / Akademicheskaya 20, Ekaterinburg 620990
  • Олег Н. Чупахин Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Ekaterinburg 620002 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, ul. S. Kovalevskoi 22 / Akademicheskaya 20, Ekaterinburg 620990

DOI:

https://doi.org/10.1007/5096

Keywords:

ethynes, (hetero)arenes, ethenes, atom economy, СН-functionalization, nucleophilic substitution of hydrogen

Abstract

This article provides an overview of the availble literature data about direct CH-functionalization reactions used for introducing alkenyl and alkynyl groups into heterocyclic systems. The information has been systematized according to the type of the experimental procedure and the nature of the (hetero)arene moiety. The time period covered in this review starts from the first example (according to our knowledge) when ethyne moiety was introduced into azaheterocycles using СНfunctionalization in 1961, until the present time. A total of 100 references have been provided.

Authors: Dmitry S. Kopchuk, Olga S. Taniya, Albert F. Khasanov, Alexey P. Krinochkin, Igor S. Kovalev, Tatyana A. Pospelova, Grigory V. Zyryanov*, Vladimir L. Rusinov, Oleg N. Chupakhin

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Published

2019-07-23

Issue

Vol. 55 No. 6 (2019): Celebrating the 85th birthday of Professor, Academician Oleg Nikolaevich Chupakhin.

Section

Review Articles