THE VERSATILITY OF DABCO: SYNTHETIC APPLICATIONS OF ITS BASIC, NUCLEOPHILIC, AND CATALYTIC PROPERTIES. PART 1. CATALYSIS OF MORITA–BAYLIS–HILLMAN AND KNOEVENAGEL REACTIONS

Authors

  • Дмитрий И. Бугаенко M. V. Lomonosov Moscow State University, 1, Build. 3 Leninskie Gory, Moscow 119992
  • Александр В. Карчава M. V. Lomonosov Moscow State University, 1, Build. 3 Leninskie Gory, Moscow 119992
  • Марина А. Юровская M. V. Lomonosov Moscow State University, 1, Build. 3 Leninskie Gory, Moscow 119992

DOI:

https://doi.org/10.1007/5341

Keywords:

1, 4-diazabicyclo[2.2.2]octane, Morita–Baylis–Hillman adducts, base, Knoevenagel reaction, Morita–Baylis–Hillman reaction, nucleophile

Abstract

This review article covers literature data from the last 5 years regarding the various applications of 1,4-diazabicyclo[2.2.2]octane (DABCO) in organic chemistry. The frequent use of DABCO as a base, catalyst, and reagent has been reflected in the large number of publications, therefore our review will be published in 4 parts. The first part of the review is dedicated to the use of DABCO as catalyst for Morita–Baylis–Hillman and Knoevenagel reactions.

Authors: Dmitry I. Bugaenko, Alexander V. Karchava, Marina A. Yurovskaya*

Author Biographies

Дмитрий И. Бугаенко, M. V. Lomonosov Moscow State University, 1, Build. 3 Leninskie Gory, Moscow 119992

Дмитрий Иванович Бугаенко

Александр В. Карчава, M. V. Lomonosov Moscow State University, 1, Build. 3 Leninskie Gory, Moscow 119992

Александр Вахтангович Карчава

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Published

2020-02-28

Issue

Vol. 56 No. 2 (2020)

Section

Review Articles