SYNTHESIS OF 2-[2-(HYDROXYIMINO)ALKYL]-1,2-OXAZOL-5(2<i>Н</i>)-ONES

Authors

  • Елена Б. Николаенкова N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090
  • Ирина Ю. Багрянская N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090
  • Алексей Я. Тихонов N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090

DOI:

https://doi.org/10.1007/5441

Keywords:

ethyl acetoacetate, hydroxyamino oximes, imidazo[1, 2-b][1, 2]oxazolones, 1, 2-oxazol-5(2H)-ones, X-ray structural analysis

Abstract

The reaction of α-hydroxyamino oximes with ethyl acetoacetate and ethyl α-methylacetoacetate yields 2-[2-(hydroxyimino)alkyl]-1,2-oxazol-5(2H)-ones. In the reaction of alkylaromatic α-hydroxyamino oximes with ethyl acetoacetate, the intermediate imidazo[1,2-b][1,2]oxazolones were isolated, which then convert to the target compounds.

Authors: Elena B. Nikolaenkova, Irina Yu. Bagryanskaya, Alexsei Ya. Tikhonov*

Author Biographies

Елена Б. Николаенкова, N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090

н.с. Лаборатории гетероциклических соединений

Ирина Ю. Багрянская, N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090

д.х.н., в.н.с. Центра спектральных исследований

Алексей Я. Тихонов, N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090

д.х.н., доцент, г.н.с. Лаборатории гетероциклических соединений

Downloads

Published

2020-02-28

Issue

Vol. 56 No. 2 (2020)

Section

Original Papers