SYNTHESIS OF С(3)–С(8) ELEUTHESIDE BLOCKS FROM LEVOGLUCOSENONE

Authors

  • Булат Т. Шарипов Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa 450054
  • Анна Н. Давыдова Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa 450054
  • Фарид А. Валеев Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa 450054

DOI:

https://doi.org/10.1007/5640

Keywords:

2, 5-dihydrofurans, levoglucosenone, N-methylurocanates, tetraols, eleuthesides

Abstract

The synthesis of stable chiral C(3)–C(8) eleutheside blocks with the corresponding substituents was carried out on the basis of levoglucosenone. This synthetic method eliminates the possibility of aromatization of intermediate and final products to furans due to the formation of the 2,5-dihydrofuran ring at the final steps and the involvement of derivatives protected at the primary hydroxy group in the ring formation reaction.

Authors: Bulat T. Sharipov*, Anna N. Davydova, Farid A. Valeev

Author Biographies

Булат Т. Шарипов, Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa 450054

старший научный сотрудник лаборатории "Фармакофорных циклических систем"

Анна Н. Давыдова, Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa 450054

младший научный сотрудник лаборатории "Фармакофорных циклических систем"

Фарид А. Валеев, Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa 450054

заведующий лаборатории "Фармакофорных циклических систем"

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Published

2020-09-17

Issue

Vol. 56 No. 8 (2020)

Section

Original Papers