SYNTHESIS AND MESOMORPHIC PROPERTIES OF <i>trans</i>-[1,4-BIS(5-R-PYRIMIDIN-2-YL]-CYCLOHEXANES AND 1,2-BIS-(5-R-PYRIMIDIN-2-YL)ETHANES

Authors

  • М. А. Михалева Novosibirsk Institute of Organic Chemistry of the Siberian Division of the Russian Academy of Sciences
  • A. E. Кузнецова Novosibirsk Institute of Organic Chemistry of the Siberian Division of the Russian Academy of Sciences

DOI:

https://doi.org/10.1007/575

Abstract

New trans-bis(5-R-pyrimidin-2-yl)-1,4-cyclohexanes and -1,2-ethanes (R=C7H15, C6H4OR1, where R1=H, COCH3, C4H9, C5H11, C8H17) have been synthesized. Only nematic mesophases are found from a study of their mesomorphic properties, except for bis[5-(4-octyloxyphenyl)- and -(4-acetoxyphenyl)pyrimidin-2-yl]-cyclohexanes, which also exhibit smectic properties.

Authors: M. A. Mikhaleva and A. E. Kuznetsova.

English Translation in Chemistry of Heterocyclic Compounds, 1999, 35 (3), pp 310-315

http://link.springer.com/article/10.1007/BF02259361

Published

2013-05-08

Issue

Section

Original Papers