SYNTHESIS OF CONDENSED SYSTEMS CONTAINING THE TETRAZOLE RING BY BASE-CATALYZED INTRAMOLECULAR CYCLIZATION OF QUATERNARY AMMONIUM SALTS

Authors

  • Э. O. Чухаджян Institute of Organic Chemistry, National Academy of Sciences of the Republic of Armenia
  • К. Г. Шахатуни Institute of Organic Chemistry, National Academy of Sciences of the Republic of Armenia
  • Эл. O. Чухаджян Institute of Organic Chemistry, National Academy of Sciences of the Republic of Armenia
  • Н. T. Геворкян Institute of Organic Chemistry, National Academy of Sciences of the Republic of Armenia

DOI:

https://doi.org/10.1007/580

Abstract

Quaternary ammonium salts containing propargyl and 3-(2-methyltetrazol-5-yl)propargyl groups undergo base-catalyzed cyclization at room temperature with self heating to form condensed heterocyclic systems containing the tetrazole ring. Heating at 90-92°C for 2 h is necessary to cyclize the allyl analogs of the starting salts.

Authors: E. O. Chukhadzhyan, K. G. Shakhatuni, El. O. Chukhadzhyan, and N. T. Gevorkyan.

English Translation in Chemistry of Heterocyclic Compounds, 1999, 35 (3), pp 343-347

http://link.springer.com/article/10.1007/BF02259366

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Published

2013-05-09

Issue

No. 3 (1999)

Section

Original Papers