NASCN–(NH<SUB>4</SUB>)<SUB>2</SUB>CE(NO<SUB>3</SUB>)<SUB>6</SUB> SYSTEM IN HETEROCYCLE THIOCYANATION: SYNTHESIS OF NOVEL HIGHLY POTENT BROAD-SPECTRUM FUNGICIDES FOR CROP PROTECTION

Authors

  • Михаил Ю. Шарипов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia D. Mendeleyev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Ave., Moscow 119991, Russia
  • Игорь Б. Крылов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia D. Mendeleyev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia State Scientific Institution ''All-Russian Research Institute of Phytopathology'', Possesion 5, Institute St., Bolshie Vyazemy 143050, Odintsovo distr., Moskow reg., Russia
  • Иван Д. Карпов D. Mendeleyev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Ave., Moscow 119991, Russia
  • Ольга В. Василькова D. Mendeleyev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Ave., Moscow 119991, Russia
  • Анна-Мария В. Алексеенко D. Mendeleyev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Ave., Moscow 119991, Russia
  • Александр О. Терентьев N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia D. Mendeleyev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia State Scientific Institution ''All-Russian Research Institute of Phytopathology'', Possesion 5, Institute St., Bolshie Vyazemy 143050, Odintsovo distr., Moskow reg., Russia

DOI:

https://doi.org/10.1007/6125

Keywords:

Tcerium ammonium nitrate, pyrroles, fungicides, rhodanation, thiocyanation.

Abstract

A method for thiocyanation of pyrroles, indoles, pyrazolones, and pyrimidine-2,4,6-triones with the NaSCN–(NH4)2Ce(NO3)6 system was proposed. The most important result was the synthesis of dithiocyanated pyrroles with high fungicidal activity against various phytopathogenic fungi.

 

Author Biography

Игорь Б. Крылов, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia D. Mendeleyev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia State Scientific Institution ''All-Russian Research Institute of Phytopathology'', Possesion 5, Institute St., Bolshie Vyazemy 143050, Odintsovo distr., Moskow reg., Russia

Laboratory for Studies of Homolytic Reactions, PhD, Senior Researcher

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Published

2021-05-27

Issue

Vol. 57 No. 5 (2021)

Section

Original Papers