<i>N</i>-(ORGANYLMETHYLIDENE)BIS(CHLOROMETHYLIDENE)THIOMORPHOLIN-4-AMINES AND –SELENOMORPHOLIN-4-AMINES

Authors

  • А. В. Мартынов A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Н. А. Махаева A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • С. В. Амосова A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

DOI:

https://doi.org/10.1007/622

Keywords:

aldehydes, hydrazones, selenomorpholin-4-amine, thiomorpholin-4-amine

Abstract

The reaction of (2E,6E)-bis(chloromethylidene)thiomorpholin-4-amine and -selenomorpholin-4-amine with propionaldehyde, benzaldehyde, or 4-pyridinecarbaldehyde in benzene in the presence of catalytic amounts of formic acid gave the corresponding hydrazones, the N-(organylmethylidene)-(2E,6E)bis(chloromethylidene)thiomorpholin-4-amines and -selenomorpholin-4-amines, as trans isomers. The structure of the hydrazones was confirmed by 1H and 13C NMR, as well as 2D 1H–1H NOESY experiments.

Authors: A. V. Martynov, N. A. Makhaeva, and S. V. Amosova.

English Translation in Chemistry of Heterocyclic Compounds, 2013, 49 (5), pp 797-801

http://link.springer.com/article/10.1007/s10593-013-1311-4

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Published

2013-05-17

Issue

No. 5 (2013)

Section

Original Papers