NUCLEOPHILIC DEAROMATIZATION OF 3-NITROBENZOFURANS BY THE ACTION OF 2-(1-ARYLETHYLIDENE)MALONONITRILES

Authors

  • Дмитрий В. Осипов Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia
  • Дарья А. Ращепкина Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia
  • Алина А. Артёменко Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia
  • Олег П. Демидов North Caucasus Federal University, 1a Pushkina St., Stavropol 355009, Russia
  • Виталий А. Осянин Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia

DOI:

https://doi.org/10.1007/6275

Keywords:

2-(1-arylethylidene)malononitriles, 1, 1-dicyanopenta-2, 4-dien-1-ide anion, 3-nitrobenzofurans, Michael reaction, nucleophilic dearomatization.

Abstract

When 2-(1-arylethylidene)malononitriles act upon 3-nitrobenzofurans in the presence of triethylamine, the furan ring opens and triethylammonium 2-aryl-1,1-dicyano-5-nitropenta-2,4-dien-1-ides are formed. The obtained salts containing the chromophoric 1,1-dicyanopentadienide fragment are of interest as anionic polymethine dyes.

 

Author Biographies

Дмитрий В. Осипов, Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia

к.х.н., доцент кафедры органической химии

Дарья А. Ращепкина, Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia

аспирант кафедры органической химии

Виталий А. Осянин, Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia

д.х.н., профессор кафедры органической химии

Downloads

Published

2021-10-21

Issue

Vol. 57 No. 10 (2021)

Section

Original Papers