PHOTOCHEMICAL OXIDATION OF 4H-SELENO(THIO)PYRANS

Authors

  • Б. И. Древко N. G. Chernyshevskii Saratov State University
  • Л. А. Фоменко N. G. Chernyshevskii Saratov State University
  • М. А. Сучков N. G. Chernyshevskii Saratov State University
  • B. Г. Харченко N. G. Chernyshevskii Saratov State University

DOI:

https://doi.org/10.1007/655

Abstract

Oxidation of solutions of 4H-thiopyrans and 4H-selenopyrans to the corresponding heteroaromatic cation bromide occurs on irradiation with ultraviolet light in the presence of CBr4. Reaction takes place by a free radical chain mechanism. The presence of CHBr3 and C2Br6 in the reaction mixture was detected chromatographically.

Authors: B. I. Drevko, L. A. Fomenko, M. A. Suchkov, and V. G. Kharchenko.

English Translation in Chemistry of Heterocyclic Compounds, 1999, 35 (6), pp 663-665

http://link.springer.com/article/10.1007/BF02251622

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Published

2013-05-30

Issue

No. 6 (1999)

Section

Original Papers