NITROMETHYLIDENE-CONTAINING PIPERAZINONES AND MORPHOLINONE: SYNTHESIS AND STRUCTURE

Authors

  • Василий В. Пелипко Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186, Russia
  • Руслан И. Байчурин Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186, Russia
  • Константин А. Лысенко Lomonosov Moscow State University, 1, Build 3 Leninskie Gory, Moscow 119991, Russia
  • Сергей В. Макаренко Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186, Russia

DOI:

https://doi.org/10.1007/7247

Keywords:

2-aminoethanol, 1, 2-diaminocyclohexane, 2-diaminoethane, 2-diaminopropane, morpholin-2-one, nitroacrylate, piperazin-2-one.

Abstract

The interactions of alkyl 3-bromo-3-nitroacrylates with 1,2-diaminoethane, 1,2-diaminopropane, 1,2-diaminocyclohexane, and 2aminoethanol were shown to provide a convenient route for the synthesis of six-membered heterocycles – (3Z)-3-(nitromethylidene)piperazin-2-ones and (3Z)-3-(nitromethylidene)morpholin-2-one. The structures of the synthesized heterocycles were characterized by a range of spectral methods and by X-ray structural analysis.

 

Author Biographies

Василий В. Пелипко, Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186, Russia

Д.х.н., доцент.

Факультет химии РГПУ им. А.И. Герцена - декан

Кафедра органической химии РГПУ им. А.И.Герцена - заведующий кафедрой.

ЦКП при факультете химии РГПУ им. А.И.Герцена - директор

Руслан И. Байчурин, Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186, Russia

к.х.н., старший научный сотрудник лаборатории нитросоединений РГПУ им. А. И. Герцена

Константин А. Лысенко, Lomonosov Moscow State University, 1, Build 3 Leninskie Gory, Moscow 119991, Russia

к.х.н.,доцент кафедры органической химии РГПУ им. А. И. Герцена

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Published

2023-05-30

Issue

Vol. 59 No. 4/5 (2023)

Section

Short Communications