STRUCTURAL INVESTIGATION OF 1-(N,N-DIMETHYLAMINOMETHYL)SPIROBI(3-OXO-2,5-DIOXA-1-SILACYCLOPENTAN)ATES
DOI:
https://doi.org/10.1007/7305Keywords:
electrostatically stabilized silanates, PM6 method, X-ray structural analysisAbstract
1-[(N,N-Dimethyl)aminomethyl]spirobi(3-oxo-2,5-dioxa-1-silacyclopentan)ate and 1-(N,N-dimethyl)-aminomethyl]spirobi(4,4-dimethyl-3-oxo-2,5-dioxa-1-silacyclopentan)ate are representatives of amino-methylspirobi(3-oxo-2,5-dioxa-1-silacyclopentan)ates, which are electrostatically stabilized silanates (ES silanates). X-ray diffraction structural analysis and quantum-chemical calculations were used in a structural study of these compounds. The factors affecting the geometry of these molecules are discussed.How to Cite
Belyakov, S.; Erchak, N.; Zheimote, S.; Fleisher, M.; Lukevics, E. Chem. Heterocycl. Compd. 2008, 44, 1520. [Khim. Geterotsikl. Soedin. 2008, 1873.]
For this article in the English edition see DOI 10.1007/s10593-009-0218-6