SYNTHESIS OF AZINYL AZOLYL PYRIMIDINES AS NEW HYBRID <i>N</i>,<i>N</i>,<i>N</i>-TRIDENTATE LIGANDS FOR COORDINATION CHEMISTRY

Authors

  • Елена Б. Николаенкова N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090
  • Никита A. Шеховцов Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Akademika Lavrentieva Ave., Novosibirsk 630090
  • Марк Б. Бушуев Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Akademika Lavrentieva Ave., Novosibirsk 630090
  • Виктор П. Кривопалов N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090

DOI:

https://doi.org/10.1007/7458

Keywords:

3-(dimethylamino)-1-(pyridin-2-yl)-2-propen-1-one, Fe(II) complexes, heterocyclic carboxamidines, 2-(pyrazin-2-yl)-4-(1H-pyrazol-1-yl)pyrimidines, 2-(1H-pyrazol-1-yl)-4-(pyridin-2-yl)-6-R-pyrimidines, 4-(1H-pyrazol-1-yl)-2-(pyridin-2-yl)-6-R-pyrimidines, 4-(1H-pyrazol-1-yl)-2-(pyrimidin-2-yl)pyrimidines, 1-(pyridin-2-yl)butane-1, 3-dione, tridentate ligands

Abstract

Routes were proposed for the synthesis of new pyrimidine-derived polycyclic nitrogen heterocycles – 4-(1H-pyrazol-1-yl)-2-(pyridin-2yl)pyrimidines with various donor substituents, isomeric 2-(1H-pyrazol-1-yl)-4-(pyridin-2-yl)pyrimidines, 2-(pyrazin-2-yl)-4-(1H-pyrazol-1-yl)pyrimidines, and 4-(1H-pyrazol-1-yl)-2-(pyrimidin-2-yl)pyrimidines – which are of interest as N,N,N-tridentate ligands for the synthesis of transition metal coordination compounds. Experimental and theoretical studies of the electronic structure of the resulting compounds were carried out.

Authors: Elena B. Nikolaenkova*, Nikita А. Shekhovtsov, Mark B. Bushuev*, Victor P. Krivopalov

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Published

2023-11-01

Issue

Vol. 59 No. 9/10 (2023)

Section

Original Papers