[2+3] CYCLOADDITION REACTION OF A KINETICALLY STABILIZED DISTIBENE WITH A NITRILE OXIDE LEADING TO THE FORMATION OF A UNIQUE HETEROCYCLIC COMPOUND

Authors

  • T. Sasamori Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011
  • E. Mieda Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011
  • N. Nagahora Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011
  • N. Tokitoh Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011

DOI:

https://doi.org/10.1007/7735

Keywords:

distibene, nitrile oxide, 1, 5, 2, 3-oxazadistibacylopent-4-ene, cycloaddition, X-ray crystallographic analysis

Abstract

The synthesis of a 1,5,2,3-oxazadistibacyclopent-4-ene derivative by the [2+3] cycloaddition reaction of a kinetically stabilized distibene, BbtSb=SbBbt (Bbt = 2,6-bis[bis(trimethylsilyl)-methyl]-4-[tris(trimethylsilyl)methyl]phenyl) with MesCNO (Mes = mesityl) has been performed.

How to Cite
Sasamori, T.; Mieda, E.; Nagahora, N.; Tokitoh, N.  Chem. Heterocycl. Compd. 2006, 42, 1603. [Khim. Geterotsikl. Soedin. 2006, 1880.]

For this article in the English edition see DOI 10.1007/s10593-006-0284-y

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Published

2023-04-25

Issue

No. 12 (2006)

Section

Original Papers