OXIDATIVE REACTIONS OF AZINES.12. DEHYDROGENATION AND OXIDATION OF 2-METHYL-9-PHENYL-2,3-DIHYDRO-1H-2-AZAFLUORENE

Authors

  • С. В. Волков Russian Peoples Friendship University, Moscow 117198
  • А. Н. Левов Russian Peoples Friendship University, Moscow 117198
  • О. Е. Волкова Russian Peoples Friendship University, Moscow 117198
  • Н. М. Колядина Russian Peoples Friendship University, Moscow 117198
  • К. Б. Полянский Russian Peoples Friendship University, Moscow 117198
  • А. Т. Солдатенков Russian Peoples Friendship University, Moscow 117198

DOI:

https://doi.org/10.1007/7984

Keywords:

2-azafluorene, anhydro base, 2, 3-dihydro-1H-2-azafluorene, manganese dioxide, indeno-[2, 1-c]pyridines, potassium permanganate, dehydrogenation, oxidation

Abstract

The oxidation of 2-methyl-9-phenyl-2,3-dihydro-1H-2-azafluorene by air, manganese dioxide, and potassium permanganate has been studied. Depending on the nature of the oxidant it was found that this dihydroazafluorene derivative can be dehydrogenated to the indeno[2,1-c]pyridine anhydro base series, be hydroxylated, oxygenated, or undergo fission to a 2-formamidomethyl-substituted indan-1-one.

How to Cite
Volkov, S. V.; Levov, A. N.; Volkova, O. E.; Kolyadina, N. M.; Polyanskii, K. B.;
Soldatenkov, A. T.  Chem. Heterocycl. Compd. 2006, 42, 636. [Khim. Geterotsikl. Soedin. 2006, 724.]

For this article in the English edition, see DOI 10.1007/s10593-006-0139-6

 

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Published

2023-08-21

Issue

No. 5 (2006)

Section

Original Papers