EFFECT OF DIFFERENT SUBSTITUENTS ON AMINE–IMINE TAUTOMERISM OF 2-AMINO-4-METHYLTHIAZOLE DERIVATIVES

Authors

  • А. П. Енгоян Armenian Agricultural Academy, Yerevan 375009
  • К. А. Элиазян Armenian Agricultural Academy, Yerevan 375009
  • В. А. Пивазян Armenian Agricultural Academy, Yerevan 375009
  • Э. А. Казарян Armenian Agricultural Academy, Yerevan 375009
  • В. В. Довлатян Armenian Agricultural Academy, Yerevan 375009

DOI:

https://doi.org/10.1007/8229

Keywords:

esters and amides of thiazole-5-carboxylic acid and thiazole-5-carbamic acid, amine–imine tautomerism

Abstract

We have used 1H NMR to study the amine–imine tautomerism of some esters and amides of 2-N-labeled 4-methylthiazole-5-carboxylic acids and 5-carbamic acids. We have shown that the nature of the substituents of the 2-NHR1, 5-COR2, or 5-NHCOR2
groups affects that position of the tautomeric equilibrium.

How to Cite
Hyengoyan, A. P.; Eliazyan, K. A.; Pivazyan, V. A.; Khazaryan, E. A.; Dovlatyan, V. V.  Chem. Heterocycl. Compd. 2005, 41, 1071. [Khim. Geterotsikl. Soedin. 2005, 1250.]

For this article in the English edition, see DOI 10.1007/s10593-005-0280-7

Published

2023-10-30

Issue

Section

Original Papers