CONDENSED TETRAZOLO-1,3,5-TRIAZINES. 2. ALKYLATION AND NUCLEOPHILIC SUBSTITUTION OF 5-TRINITROMETHYLTETRAZOLO[1,5-<i></i>a]-1,3,5-TRIAZIN-7-ONES

Authors

  • Б. С. Федоров Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region
  • А. Н. Утенышев Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region
  • А. А. Гидаспов Samara State Technical University, 443010 Samara
  • Е. В. Качановская Samara State Technical University, 443010 Samara
  • В. В. Бахарев Samara State Technical University, 443010 Samara
  • М. А. Фадеев Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region

DOI:

https://doi.org/10.1007/8330

Keywords:

condensed tetrazolo-1, 3, 5-triazines, 5-aryloxy-3-methyl- and 5-arylthio-3-methyltetrazolo[1, 5-a]-1, 5-triazin-7-ones, 3-methyl-5-trinitromethyltetrazolo[1, 5-triazin-7-one, alkylation, nucleophilic substitution of the trinitromethyl group

Abstract

A  new heterocyclic compound, 3-methyl-5-trinitromethyltetrazolo[1,5-a]-1,3,5-triazin-7-one, was synthesized by the reaction of methyl iodide and the silver salt of 5-trinitromethyltetrazolo[1,5-a]-1,3,5-triazin-7-one. An X-ray diffraction structural analysis of this product was carried out and feasibility was demonstrated for the nucleophilic substitution of the trinitromethyl group in this compound by the action of phenol, phenol derivatives, and thiophenol.

How to Cite
Fedorov, B. S.; Utienyshev, A. N.; Ghidaspov, A. A.; Kachanovskaya, E. V.; Bakharev, V. V.; Fadeev, M. A.  Chem. Heterocycl. Compd. 2005, 41, 496. [Khim. Geterotsikl. Soedin. 2005, 582.]

For this article in the English edition, see DOI 10.1007/s10593-005-0178-4


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Published

2023-11-17

Issue

No. 4 (2005)

Section

Original Papers