HYDROSILYLATION OF (HETERO)AROMATIC ALDIMINES IN THE PRESENCE OF A Pd(I) COMPLEX

Authors

  • I. Iovel Latvian Institute of Organic Synthesis, Riga LV 1006
  • L. Golomba Latvian Institute of Organic Synthesis, Riga LV 1006
  • M. Fleisher Latvian Institute of Organic Synthesis, Riga LV 1006
  • J. Popelis Latvian Institute of Organic Synthesis, Riga LV 1006
  • S. Grinberga Latvian Institute of Organic Synthesis, Riga LV 1006
  • E. Lukevics Latvian Institute of Organic Synthesis, Riga LV 1006

Keywords:

transition metal complexes, Schiff bases, hydrosilylation, catalysis

Abstract

The reaction of triethylsilane with heterocyclic and aromatic azomethines, catalyzed by the [Pd(allyl)Cl]2 complex, was studied. It was found that the reaction is affected by the nature of the functional groups in the aza and methine parts of the aldimine molecules, which were produced by the condensation of furan, thiophene, and benzene aldehydes with aniline and its derivatives. The reactivity of a series of imines is compared with their electronic and structural characteristics, determined by quantum-chemical methods. The corresponding furan, thiophene, and aromatic amines and also certain silylamines were synthesized.

How to Cite
Iovel, I.; Golomba, L.; Fleisher, M.; Popelis, J.; Grinberga, S.; Lukevics, E. Chem. Heterocycl. Compd. 2004, 40, 701. [Khim. Geterotsikl. Soedin. 2004, 825.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000040765.61681.f0

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Published

2004-06-25

Issue

No. 6 (2004)

Section

Original Papers