INVESTIGATION OF H-COMPLEX FORMATION OF DERIVATIVES OF NAPHTHALIMIDE WITH PHENOL BY IR SPECTROSCOPY

Authors

  • В. М. Шершуков Institute of Monocrystals, National Academy of Sciences (NAN) of Ukraine, Kharkov 61001
  • Р. А. Минакова Institute of Monocrystals, National Academy of Sciences (NAN) of Ukraine, Kharkov 61001
  • А. И. Бедрик Institute of Monocrystals, National Academy of Sciences (NAN) of Ukraine, Kharkov 61001
  • Ю. Н. Суров Institute of Monocrystals, National Academy of Sciences (NAN) of Ukraine, Kharkov 61001

Keywords:

naphthalic acid imides, H-complex formation, proton donor, reaction center, IR spectroscopy

Abstract

The H-complex-forming reaction of naphthalimide derivatives with phenol has been investigated by IR spectroscopy. It was shown that for the majority of compounds studied the carbonyl group is the main center of basicity. In the case of amino-substituted imides of naphthalic acid transfer is possible of the reaction center from the carbonyl group to the nitrogen atom of the substituent introduced into the naphthalene ring. However because of steric hindrance this occurs only for amino- and methylamino-substituted naphthalimide.

How to Cite
Shershukov, V. M.; Minakova, R. A.; Bedrik, A. I.; Surov, Yu. N. Chem. Heterocycl. Compd. 2004, 40, 456. [Khim. Geterotsikl. Soedin. 2004, 551.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000033537.75831.2f

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Published

2004-04-25

Issue

No. 4 (2004)

Section

Original Papers