HETEROCYCLIC DERIVATIVES OF FULLERENE C<sub>60</sub>. 1. SYNTHESIS OF NEW FULLEROPYRAZOLINES BY THE 1,3-DIPOLAR CYCLOADDITION OF NITRILE IMINES

Authors

  • М. В. Рейнов Moscow M. V. Lomonosov State University, Moscow 119234
  • М. А. Юровская Moscow M. V. Lomonosov State University, Moscow 119234
  • Д. В. Давыдов Moscow M. V. Lomonosov State University, Moscow 119234
  • А. В. Стрелецкий Moscow M. V. Lomonosov State University, Moscow 119234

Keywords:

hydrazonoyl halides, 2,5-diaryltetrazoles, [6,6]-closed cycloadducts, nitrile imines, fullerene C60, fulleropyrazolines, 1,3-dipolar cycloaddition

Abstract

New stable [6,6]-closed cycloadducts, fulleropyrazolines containing aryl, hetaryl, trifluoromethyl, and other substituents in the five-membered ring, have been obtained by the 1,3-dipolar cycloaddition of nitrile imines to C60. Two methods of generating nitrile imines in situ have been used, the dehydro-halogenation of the corresponding hydrazonoyl halides by the action of triethylamine and the thermal decomposition of 2,5-diaryltetrazoles.

How to Cite
Reinov, M. V.; Yurovskaya, M. A.; Davydov, D. V.; Streletskii, A. V. Chem. Heterocycl. Compd. 2004, 40, 188. [Khim. Geterotsikl. Soedin. 2004, 223.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000027890.05668.07

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Published

2004-02-25

Issue

No. 2 (2004)

Section

Original Papers