UNUSUAL THERMAL REARRANGEMENTS OF N-CYCLOHEXYLIDENE-4-METHYL-1-(METHYLTHIO)PENTA-1,3-DIEN-1-AMINE

Authors

  • Н. А. Недоля A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • Л. Брандсма Utrecht University, 3584 CH Utrecht
  • Б. А. Трофимов A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033

Keywords:

1,1-dimethylallene, 4,4-dimethyl-2-(methylthio)-3,3a,4,4a,5,6,7,8-octahydrobenzo[4,1]cyclobuta[1,2-b]pyrrole, 1-cyclohexyl-5-methylpyridine-2(1H)-thione, cyclohexylisothiocyanate, alkylation, lithiation, rearrangement

Abstract

We have observed unusual thermal rearrangements of N-cyclohexylidene-4-methyl-1-(methylthio)penta-1,3-dien-1-amine to 4,4-dimethyl-2-(methylthio)-3,3a,4,4a,5,6,7,8-octahydrobenzo[4,1]cyclobuta-[1,2-b]pyrrole and 1-cyclohexyl-5-methylpyridine-2(1H)-thione.

How to Cite
Nedolya, N. A.; Brandsma, L.; Trofimov, B. A. Chem. Heterocycl. Compd. 2002, 38, 1230. [Khim. Geterotsikl. Soedin. 2002, 1396.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1021733614089

Downloads

Published

2002-10-25

Issue

No. 10 (2002)

Section

Original Papers