STEREOSELECTIVE METHODS FOR THE SYNTHESIS OF 4-BENZOYL-1-BENZOYLAMINO-3-(2-CHLOROPHENYL)-2-CYANO-1-METHYLTHIO-1-BUTENE AND ITS STRUCTURE

Authors

  • С. Г. Кривоколыско East-Ukraine State University, Lugansk 91034
  • Э. Б. Русанов Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev 02094
  • В. П. Литвинов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 117913

Keywords:

1-butene, tetrahydro-2-pyridinethiolates, methylation, X-ray crystallographic analysis

Abstract

Selective methods were developed for the synthesis of 4-benzoyl-1-benzoylamino-3-(2-chlorophenyl)-2-cyano-1-methylthio-1-butene on the basis of the reaction of N-methylmorpholinium and piperidinium 5-benzoyl-4-(2-chlorophenyl)-3-cyano-6-hydroxy-6-phenyl-1,4,5,6-tetrahydropyridine-2-thiolates with methyl iodide. The structure of the product was established by X-ray crystallographic analysis.

How to Cite
Krivokolysko, S. G.; Rusanov, E. B.; Litvinov, V. P. Chem. Heterocycl. Compd. 2002, 38, 1205. [Khim. Geterotsikl. Soedin. 2002, 1369.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1021729513180

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Published

2002-10-25

Issue

No. 10 (2002)

Section

Original Papers