STRUCTURAL CHARACTERIZATION OF A PENTACOORDINATE MONOHYDROSILANE WITH THE APICAL Si–H BOND

Authors

  • K. Saruhashi Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-Ku, Tokyo 113-0033
  • K. Goto Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-Ku, Tokyo 113-0033
  • T. Kawashima Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-Ku, Tokyo 113-0033

Keywords:

hydrosilane, apicophilicity, intramolecular N–Si coordination

Abstract

A pentacoordinate phenyldibenzosilazocine containing the apical Si–H bond has been prepared and characterized by 1H and 29Si NMR spectra and X-ray analysis.

How to Cite
Saruhashi, K.; Goto, K.; Kawashima, T. Chem. Heterocycl. Compd. 2001, 37, 1394. [Khim. Geterotsikl. Soedin. 2001, 1524.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1017903318391

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Published

2001-11-25

Issue

No. 11 (2001)

Section

Original Papers