REACTION OF 2-(2-AZAHETARYL)-4-CHLORO-3-OXOBUTYRONITRILES WITH SUBSTITUTED BENZALDEHYDE HYDRAZONES. UNEXPECTED FORMATION OF 4-ARYLIDENEAMINO-2-(1-R-BENZIMIDAZOL-2-YL)-3-OXOBUTYRONITRILES

Authors

  • Ю. М. Воловенко Taras Shevchenko University, Kiev 252601
  • А. В. Твердохлебов Taras Shevchenko University, Kiev 252601
  • Т. А. Воловненко Taras Shevchenko University, Kiev 252601

Keywords:

2-(2-azahetaryl)-4-chloro-3-oxobutyronitriles, 4-arylideneamino-2-(1-R-benzimidazol-2-yl)-3-oxobutyronitriles, hydrazones, benzaldehydes

Abstract

The reaction of 2-(2-azahetaryl)-3-oxo-4-chlorobutyronitriles with substituted benzaldehyde hydrazones gives 4-arylideneamino-2-(1-R-benzimidazol-2-yl)-3-oxobutyronitriles, the structures of which were proved using spectroscopic data, the results of elemental analysis, and through their chemical reactions. It was found that the reaction course depends on the basicity of the heterocyclic fragment in the starting nitrile. A likely mechanism for the process is proposed.

How to Cite
Volovenko, Yu. M.; Tverdokhlebov, A. V.; Volovnenko, T. A. Chem. Heterocycl. Compd. 2001, 37, 876. [Khim. Geterotsikl. Soedin. 2001, 952.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1012407826196

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Published

2001-07-25

Issue

No. 7 (2001)

Section

Original Papers