SYNTHESES OF HETEROCYCLES FROM THE SODIUM SALTS OF 3-(1-ADAMANTYL)-1-HYDROXY-1-PROPEN-3-ONE AND 4-(1-ADAMANTYL)-1-HYDROXY-1-BUTEN-3-ONE
Keywords:
(1-adamantyl)acetone, 2-aminopyrimidines, 5-hydroxy-Δ<sup>2</sup>-isoxazolines, 3-(1-adamantyl)-1-hydroxy-1-propen-3-one sodium salt, , 4-(1-adamantyl)-1-hydroxy-1-buten-3-one sodium salt, pyrazoles, cyclizationAbstract
The interaction of the sodium salts of 3-(1-adamantyl)-1-hydroxy-1-propen-3-one and 4-(1-adamantyl)-1-hydroxy-1-buten-3-one with hydroxylamine, hydrazine, and guanidine leads to the synthesis of 5‑(1‑adamantyl)-5-hydroxy- and 5-(1-adamantylmethyl)-5-hydroxy-Δ2-isoxazolines, 3-(1-adamantyl)- and 3-(1-adamantylmethyl)pyrazoles, 3-(1-adamantyl)-2-phenylpyrazole, and 4-(1-adamantyl)-2-amino- and 4-(1-adamantylmethyl)-2-aminopyrimidines.
How to Cite
Makarova, N. V.; Zemtsova, M. N.; Moiseev, I. K. Chem. Heterocycl. Compd. 2001, 37, 840. [Khim. Geterotsikl. Soedin. 2001, 912.]
For this article in the English edition, see DOI https://doi.org/10.1023/A:1012443306632
