SYNTHESIS OF FURAN AND DIHYDROFURAN DERIVATIVES <i>via</i> FEIST–BENARY REACTION IN THE PRESENCE OF AMMONIUM ACETATE IN AQUEOUS ETHANOL
DOI:
https://doi.org/10.1007/2824Ключевые слова:
1, 3-dicarbonyl compounds, dihydrofuran, ethyl bromopyruvate, furan, phenacyl bromide, Feist–Benary reactionАннотация
An efficient synthesis of dihydrofurans and furans by a reaction between 1,3-dicarbonyl compounds and ethyl bromopyruvate, ethyl 2-chloroacetoacetate, or 3-chloroacetylacetone in the presence of ammonium acetate in aqueous ethanol is described. When the reaction was performed with a phenacyl bromide, O-alkylation of 1,3-dicarbonyl compounds occurred without cyclization.
How to Cite
Ghazvini, M.; Shahvelayati, A. S.; Sabri, A.; Zeinali Nasrabadi, F. Chem. Heterocycl. Compd. 2016, 52, 161. [Khim. Geterotsikl. Soedin. 2016, 52, 161.]
For this article in the English edition see DOI 10.1007/s10593-016-1854-2
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Опубликован
2016-04-11
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Оригинальные статьи