SYNTHESIS OF THE FIRST DITHIAAZA-17-CROWN-5 ETHERS CONTAINING PIPERIDIN-4-ONE SUBUNIT
DOI:
https://doi.org/10.1007/6277Ключевые слова:
dithiaaza-17-crown-5 ether, 2, 2'-[ethane-1, 2-diylbis(oxyethane-2, 1-diylsulfanediyl)]dibenzaldehyde, domino reaction, Petrenko– Kritschenko reaction.Аннотация
Dithiaaza-17-crown-5 ethers containing piperidin-4-one subunit and dithiacrown ether fragment were synthesized in one-pot Petrenko–Kritschenko reaction from 2,2'-[ethane-1,2-diylbis(oxyethane-2,1-diylsulfanediyl)]dibenzaldehyde, methyl ethyl ketone or dibenzyl ketone, and ammonium acetate. Molecular structure of dithiaaza-17-crown-5 ethers were confirmed by NMR, HRMS, and single crystal X-ray diffraction.
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2021-10-21
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