SYNTHESIS OF FUNCTIONALIZED POLYHALOGENATED THIOPHENE DERIVATIVES

Авторы

  • Nikita A. Chaika National Technical University of Ukraine ''Igor Sikorsky Kyiv Polytechnic Institute'', 37 Peremohy Ave., Kyiv 03056, Ukraine
  • Kostiantyn V. Shvydenko Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Akademika Kukharya St., Kyiv 02094, Ukraine
  • Tetiana I. Shvydenko Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Akademika Kukharya St., Kyiv 02094, Ukraine
  • Aleksandr N. Kostyuk ИОХ НАН Украины

DOI:

https://doi.org/10.1007/7482

Ключевые слова:

diethylaminosulfur trifluoride, diiodothiophenes, polyhalogenated thiophenes, formylation, halogen dance reaction.

Аннотация

The halogen dance reaction was utilized for preparation of iodothiophenes. Starting from a set of dihalo-substituted thiophenes, their derivatives, namely, aldehydes, acids, and 2,5-diiodothiophenes, were obtained. Formyl derivatives of thiophenes served as the basis for the synthesis of a number of previously unknown (difluoromethyl)- and (chloromethyl)thiophenes. Convenient and simple synthetic procedures were developed for a set of functionalized thiophenes.

Биография автора

Aleksandr N. Kostyuk, ИОХ НАН Украины

зав. отделом химии фосфорорганических соединений

Загрузки

Опубликован

2023-08-09

Выпуск

Том 59 № 6/7 (2023): UKRAINIAN IMPACT ON HETEROCYCLIC CHEMISTRY AFTER THE THREE DECADES OF INDEPENDENCE

Раздел

Оригинальные статьи