DERIVATIVES OF 4-CARBOXY-3,5-DIPHENYL-2-PHENYLIMINOTHIAZOLINE. SYNTHESIS AND MASS SPECTRAL INVESTIGATION

Authors

  • B. А. Мамедов A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
  • И. З. Нурхаметова A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
  • И. Х. Ризванов A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
  • Ю. Я. Ефремов A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
  • Я. А. Левин A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1080

Abstract

Methods have been developed for dehydrating the unusually stable intermediate products of the Hantzsch reaction of N,N'-diphenylthioureas with derivatives of phenylchloropyruvic acid, viz. 4-hydroxy-4-methoxy(diethylamino)carbonyl-3,5-diphenyl-2-phenyliminothiazolidines, into the corresponding 4-methoxy(diethylamino)carbonyl-3,5-diphenyl-2-phenyliminothiazolines. Characteristic features of the dissociative ionization of the latter and their anilide analog under the action of electron impact have been clarified.

Authors: V. A. Mamedov, I. Z. Nurkhametova, I. Kh. Rizvanov, Yu. Ya. Efremov, and Ya. A. Levin.

English Translation in Chemistry of Heterocyclic Compounds, 1999, 35 (11), pp 1364-1369

http://link.springer.com/article/10.1007/BF02252010

 

Published

2013-10-29

Issue

Section

Original Papers