REACTIONS OF 4-ARYL-1,2,4-TRIAZOLIDINE-3,5-DITHIONE WITH SOME ELECTROPHILIC REAGENTS

Authors

  • И. М. Базавова Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • В. Н. Брицун Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • А. Н. Есипенко Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • В. М. Неплюев Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • М. О. Лозинский Institute of Organic Chemistry, National Academy of Sciences of Ukraine

DOI:

https://doi.org/10.1007/314

Keywords:

4-aryl-1, 2, 4-triazole-3, 5-bis(sulfides), 1-(aminomethyl)-4-aryl-1, 4-triazolidine-3, 5-dithiones

Abstract

Reaction of 4-aryl-1,2,4-triazolidine-3,5-dithiones in an alkaline medium with chloroacetic acid and its derivatives, as well as with α-bromo ketones, results in their conversion to 4-aryl-1,2,4-triazole-3,5-bis(sulfides). The aminomethylation in a neutral medium leads to the formation of 1-(aminomethyl)-4-aryl-1,2,4-triazolidine-3,5-dithiones.

Authors: I. M. Bazavova, V. N. Britsun, A. N. Esipenko, V. M. Neplyuev, and M. O. Lozinsky.

English Translation in Chemistry of Heterocyclic Compounds, 2000, 36 (9), pp 1058-1061

http://link.springer.com/article/10.1023/A%3A1002733931905

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Published

2013-02-14

Issue

No. 9 (2000)

Section

Original Papers