SYNTHESIS AND PROPERTIES OF 2-(2-FURYL)-1-METHYL-1H-ACENAPHTHO[9,10-<i>d</i>]IMIDAZOLE
DOI:
https://doi.org/10.1007/8051Keywords:
9, 10-аценафтенхинон, 2-(2-фурил)-1Н-аценафто[9, 10-d]имидазол, метилирование, реакции электрофильного замещенияAbstract
2-(2-Furyl)-1-methyl-1H-acenaphtho[9,10-d]imidazole was obtained by the condensation of 9,1-acenaphthenequinone with furfural in the presence of ammonium acetate followed by N-methylation of the obtained 2-(2-furyl)-1H-acenaphtho[9,10-d]imidazole with methyl iodide in N-methylpyrrolid-2-one in the presence of potassium hydroxide. It was established that its electrophilic substitution in an acidic medium only takes place at position 2 of the furan ring while in a neutral medium both position 2 and position 7 of the aromatic part of the molecule undergo electrophilic attack.How to Cite
Achkasova, A. A.; El'chaninov, M. M. Chem. Heterocycl. Compd. 2006, 42, 166. [Khim. Geterotsikl. Soedin. 2006, 191.]
For this article in the English edition, see DOI 10.1007/s10593-006-0065-7
