MOLECULAR AND CRYSTAL STRUCTURE OF 4,6-DIMETHYL-2-(PHENYLHYDRAZINO)PYRIMIDINE AND ITS ALKYLATION AND PROTONATION PRODUCTS

Authors

  • Б. И. Бузыкин A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan 420088
  • М. Ю. Сорокин A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan 420088
  • Д. Б. Криволапов A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan 420088
  • А. Т. Губайдуллин A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan 420088
  • И. А. Литвинов Институт органической и физической химии им. А. Е. Арбузова Казанского научного центра РАН, Казань 420088

Keywords:

4,6-dimethyl-2-(phenylhydrazino)pyrimidine, pyrimidine, alkylation, protonation, X-ray crystallographic analysis

Abstract

It was established by X-ray crystallographic analysis that 4,6-dimethyl-2-(phenylhydrazino)pyrimidine forms 2-(2-n-butyl-2-phenylhydrazino)-4,6-dimethylpyrimidine during alkylation with n-butyl bromide and 4,6-dimethyl-2-(phenylhydrazino)-1(H)-pyrimidinium nitrate during protonation with nitric acid. The structure of the molecules and the system of intermolecular hydrogen bonds in the crystals of the compounds are discussed.

How to Cite
Buzykin, B. I.; Sorokin, M. Yu.; Krivolapov, D. B.; Gubaidullin, A. T.; Litvinov, I. A. Chem. Heterocycl. Compd. 2002, 38, 1348. [Khim. Geterotsikl. Soedin. 2002, 1531.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1022178425960

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Published

2002-11-25

Issue

No. 11 (2002)

Section

Original Papers