SYNTHESIS OF SULFUR-CONTAINING HETEROCYCLIC COMPOUNDS BASED ON ISOTHIOCYANATE DERIVATIVES OF PERFLUOROOLEFINS
Keywords:
3-methyl-2-methylamino-6-pentafluoroethyl-5-trifluoromethyl-3H-pyrimidine-4-thione, nucleophilic reagents, perfluoro(3-isothiocyanato-2-methyl-2-pentene), 4,5-dihydrothiazole derivatives, 6H-1,3-thiazine, nucleophilic addition, intramolecular cyclizationAbstract
The paper reviews data on the synthesis of heterocyclic compounds with perfluoroalkyl groups based on
the reaction of thiocyanate and isothiocyanate derivatives of perfluoroolefins with mononucleophilic
reagents (C-, O-, S-, P-, and N-nucleophiles). It was shown that such derivatives are prospective
synthons for the production of 1,3-thiazoles and 1,3-thiazolines. The factors affecting the formation of
the heterocyclic system are identified.
How to Cite
Furin, G. G.; Zhuzhgov, E. L. Chem. Heterocycl. Compd. 2002, 38, 129. [Khim. Geterotsikl. Soedin. 2002, 147.]
For this article in the English edition, see DOI https://doi.org/10.1023/A:1015320822860
