INTRAMOLECULAR P=S AND P=N ALKYLATION. GENERAL METHOD FOR SYNTHESIZING 1,2-HETERAPHOSPHACYCLANES

Authors

  • И. М. Аладжева A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991
  • О. B. Быховская A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991
  • Д. И. Лобaнов A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991
  • П. В. Петровский A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991
  • К. А. Лысенко A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991
  • T. А. Mастрюкова A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991

Keywords:

1,2-azaphosphacyclanes, 1,2-thiaphosphacyclanes, ring–chain halotropic tautomerism, intramolecular alkylation

Abstract

Results have been generalized for investigations on the synthesis of 1,2-thiaphosphacyclanes by intramolecular P=S alkylation of ω-haloalkyl substituted compounds of four-coordinated phosphorus with a P=S bond. The method has been extended to nitrogen-containing analogs with a P=N bond. A new general method is proposed for the synthesis of 1,2-thia- and 1,2-azaphosphacyclanes.

How to Cite
Aladzheva, I. M.; Bykhovskaya, O. V.; Lobanov, D. I.; Petrovskii, P. V.; Lysenko, K. A.; Mastryukova, T. A. Chem. Heterocycl. Compd. 2002, 38, 95. [Khim. Geterotsikl. Soedin. 2002, 105.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1014815628426

Downloads

Published

2002-01-25

Issue

No. 1 (2002)

Section

Original Papers